Thursday, October 31, 2013

What factors controls the shape of a well formed crystal?

The following are major factors that influence the shape of a well formed crystal:
 
  •   Symmetry properties of the underlying lattice
  •  Rates of growth; - the overall shape of the crystal is determined by the relative rates of growth of the various faces. Thus the slower the growth rate, the larger the face. 
  • The conditions under which a crystal is grown can affect its habit. The Temperature, degree of super-saturation, nature of the solvent all have their effects, and these may affect the growth of different faces in different ways. 
  • The presence of impurities in the solution can radically alter the habit of a crystal, as seen in the following table for the growth of sodium chloride: 
no impurity           Fe(CN)64–         formamide Pb2+,             Cd2+          polyvinyl alcohol
cubes                     dendrites                octahedra              large crystals          needles

These effects presumably come about because these substances preferentially adsorb to certain faces, impeding their growth.

No comments:

Post a Comment